The issues affecting Vodafone services have also impacted customers of other telecoms firms that use its network.
Downdetector saw a similar spike in reports on Monday afternoon from users of the mobile network Voxi, which is owned by Vodafone.
Lebara, which piggy-backs off Vodafone's network, has also been affected by the company's outage.
"Outages have been reported across multiple networks across broadband and mobile services," said Sabrina Hoque, telecoms expert at Uswitch.
These, she added, can be "a really frustrating experience for customers, especially when it's not clear how long it could last".
Vodafone has not yet said how long it expects its outage to last - though its website since appears to have come back online.
Cloudflare Radar, which tracks and displays patterns in global internet traffic, said in a post on Bluesky earlier it had "effectively dropped off the internet, with traffic dropping to zero".
The company has also not said what caused the issue affecting its networks.
"Incidents like this are often caused by a technical fault or configuration error rather than a major cyber-attack, so until more details are confirmed it's best not to speculate," said Daniel Card, a cyber expert with BCS, The Chartered Institute for IT.
"Having teams capable of diagnosing and responding rapidly to network failures is key to maintaining public trust and keeping the UK's digital infrastructure running smoothly."
Additional reporting by Ewan Somerville.